

Mass Spectra
Presentation
•
Science
•
11th Grade
•
Hard
Joseph Anderson
FREE Resource
7 Slides • 12 Questions
1
Review and preview of Atomic structure

2
Multiple Choice
The nucleus of a 23Na atom contains
11 protons and 12 neutrons.
11 protons and 12 electrons.
23 protons and 11 neutrons.
11 protons and 11 electrons.
3
Multiple Choice
The mass spectrum for a sample of a metal is shown below.
The relative atomic mass of the metal is
63.2
63.4
63.6
64.0
4
Multiple Choice
Chlorine has two isotopes with relative isotopic mass 35 and 37. Four m/z values are given below. Which will occur in a mass spectrum of chlorine gas, Cl2, from an ion with a single positive charge?
35.5
36
71
72
5
Multiple Choice
Bromine has two isotopes with relative isotopic masses 79 and 81. Which of the following values for mass/charge ratio could correspond to a peak in the mass spectrum of bromine, Br2? You should assume the ions detected have a single positive charge.
79.9
80
159
160
6
Multiple Choice
Which of these statements is incorrect?
The atomic radius of metals increases down a Group.
The trend in the melting temperature of successive elements across Period 2 is similar to that in Period 3.
A metallic structure is held together by attractions between metal atoms and delocalized electrons.
Na+ and O2– ions are isoelectronic.
7
Multiple Choice
In which of the following series does the melting temperature of the element increase from left to right?
Li, Na, K
Al, Si, P
Si, P, S
Na, Mg, Al
8
Multiple Choice
The correct sequence for the processes that occur in a mass spectrometer is
vaporization, ionization, acceleration, deflection and detection.
vaporization, acceleration, ionization, deflection and detection.
ionization, vaporization, acceleration, deflection and detection.
ionization, vaporization, deflection, acceleration and detection.
9
Multiple Choice
Which of the following ions would be deflected most in a mass spectrometer?
35Cl+
37Cl+
37Cl2+
(35Cl – 37Cl)+
10
Multiple Choice
The chemical properties of an element are determined by its
electronic structure
number of neutrons.
relative atomic mass
number of protons plus neutrons.
11
Multiple Choice
In a mass spectrometer, positive ions are accelerated by
bombarding them with fast–moving electrons.
bombarding them with fast–moving protons.
passing them between charged plates.
passing them through a magnetic field.
12
Multiple Choice
Bromine has two isotopes with relative isotopic masses 79 and 81. Which of the following values for mass/charge ratio could correspond to a peak in the mass spectrum of bromine, Br2? You should assume the ions detected have a single positive charge.
79.9
80
159
160
13
Multiple Choice
Which pair of ions is isoelectronic?
Ca2+ and O2–
Na+ and O2–
Li+ and Cl–
Mg2+ and Cl–
14
Electronic Structure of the atom
The electronic structure of an atom that determines its chemical properties.
Aufbau Principle: Electrons can be regarded as having certain energy levels. The lower levels fill before the higher levels are occupied.
15
Electronic Configuration
The shells used in the simple view of the atom are divided into subshells.
Shells are also called the principal quantum number of electrons.
16
The higher the energy of the shell, the more subshells it contains.
17
Orbitals in subshells
An orbital has no edge, the surface which would contain a given percentage (say, 95%) of the electron density
Each electron in an atom is different from all the other electrons
18
s subshell
s-orbitals can contain a maximum of two electrons.
These have the same energy value, but are said to have opposite spin values (Pauli exclusion principle)
The s-orbital is always spherically symmetrical
Total number of electrons in 1s orbital = ____
19
p subshell
There are three p orbitals, each of which can contain a maximum of two electrons.
Total number of electrons in 2p orbitals = _______
Review and preview of Atomic structure

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