
Aluminum production
Presentation
•
Chemistry, Science
•
10th Grade
•
Practice Problem
•
Hard
Okapi Zebraffe
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10 Slides • 10 Questions
1
Aluminum production
2
Multiple Select
Which is true for aluminum? (structure)
BCC
1 unpaired electron
covalent bonding
atomic lattice
ionic bonding
3
Multiple Select
Which is true for aluminum oxide? (structure)
solid
red
covalent bonding
atomic lattice
ionic bonding
4
Poll
Which is the first step?
alkaline dissolution
calcination
crushing & milling
crystalisation & filtration
mining
5
Mining bauxite
its ore, bauxite (colour from an impurity) is
often dug out of the ground in open-cast mines. The ore contains hydrated aluminium oxide: reffered as Al2O3·xH2O – or sometimes Al(OH)3 - Al2O3 mixture or AlO(OH).
6
Fill in the Blanks
Type answer...
7
Poll
What is next?
alkaline dissolution
calcination
crushing & milling
crystalisation
filtration
8
Preparatory steps - physically
crushing
milling
9
Separation from impurities
hot concentrated soda lye
conversion of oxide into sodium tetrahydroxo aluminate (Na[Al(OH)4])
Al2O3 + H2O + NaOH = Na[Al(OH)4]
Al(OH)3 + NaOH = Na[Al(OH)4]
AlO(OH) + NaOH + H2O = Na[Al(OH)4]
10
Multiple Choice
Name the process
alkaline dissolution
calcination
crushing & milling
crystalisation
filtration
11
Poll
What is next?
calcination
crystalisation
filtration
smelting
12
Separation from impurities
removal of impurities
red mud
13
RED MUD
a mixture of solid and metallic oxides
red colour arises from iron oxides (up to 60w%)
pH= 10-13
silica, unleached residual alumina, and titanium oxide.
14
Multiple Choice
Name the process
alkaline dissolution
calcination
crushing & milling
crystalisation
filtration
15
Separation from impurities
extreme dilution
against equlibrium system of Na[Al(OH)4]
Na[Al(OH)4] -> Al(OH)3 + NaOH
precipitation
16
Multiple Choice
Name the process
alkaline dissolution
calcination
crushing & milling
crystalisation
filtration
17
Getting alumina
alumina (timföld) Al2O3
purification of Al2O3 .x H2O into Al2O3
ready for electrolysis?
The melting point of alumina Al2O3 is 2050°C.
18
Multiple Choice
which lattice structure does it imply?
atomic
ionic
metallic
molecular
19
Smelting - preparatory steps
Cryolite is added (Na3AlF6) to decrease the melting point below 1000°C.
1886 Charles Martin Hall and Héroult
In 1888, Hall opened the first large-scale aluminium production plant in Pittsburgh (later became the Alcoa ).
Hall–Héroult process
Al2O3→ Al + O2
20
Important aluminium alloys
Silumin: 12% Si content. → casting alloy (öntvényezés)
Duraluminium alloy: 3.5-4.5% Cu, 0.5% Mg, 0-0.5% Mn. Extreme strength
„Hydronalium” Al-Mg alloy. Corrosion resistant
„Aldrey” alloys, for electric conductivity, corrosion resistance2.8-4.5% Cu, 0.9-1.6% Mg, 0.5-1.2% Mn, 0.2-0.7% Si.
Aluminum production
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