
AP Chem Semester 01 Exam Review Units 04-06
Presentation
•
Chemistry
•
10th Grade
•
Easy
+2
Standards-aligned
Patrick Boylan
Used 212+ times
FREE Resource
0 Slides • 16 Questions
1
Multiple Choice
Based on the information above, what is the standard enthalpy change for the following reaction?
N2H4(l) + H2(g) → 2NH3(g)
-151kJ/molrxn
-935kJ/molrxn
-1119kJ/molrxn
-59kJ/molrxn
2
Multiple Choice
2Al(s) + Fe2O3(s) → 2Fe(s) + Al2O3(s)
ΔHrxn = -860kJ/molrxn
Based on the standard enthalpies of formation ΔH∘f provided in the table, what is the approximate ΔH∘f for Fe2O3(s) ?
+2540kJ/mol
−2540kJ/mol
+820kJ/mol
−820kJ/mol
3
Multiple Choice
XeF2 + 2 F2 → XeF6
ΔH°rxn = ?
NO calculator!
4
Multiple Choice
Carbon monoxide reacts with oxygen to form carbon dioxide by the following reaction:
2 CO(g) + O2(g) → 2 CO2(g) ΔH = -302.4 kJ/mol
What is the expected energy change for the reaction of three moles of O2 with four moles of CO?
-302.4 kJ/mol
-604.8 kJ/mol
-907.2 kJ/mol
-151.2 kJ/mol
5
Multiple Choice
ΔG for the entire process at constant temperature.
NO Calculator!
+ΔH, −ΔS, ΔG=0
−H, +S, ΔG=0
+ΔH, +ΔS, −ΔG
−ΔH, −ΔS, −ΔG
6
Multiple Choice
2C(s) + 2H2(g) → C2H4(g) ΔH0rxn = +52.4 kJ/molrxn
It is observed that the reaction producing C2H4(g) from its elements goes essentially to completion. Which of the following is a true statement about the thermodynamic favorability of the reaction?
The reaction is unfavorable due to both enthalpy and entropy changes.
The reaction is favorable and driven by an entropy change only.
The reaction is favorable and driven by an enthalpy change only.
The reaction is favorable and driven by both enthalpy and entropy changes.
7
Multiple Choice
CO2(g) + 2 NH3(g) → CO(NH2)2(s) + H2O(ℓ)
at 25◦C the thermodynamic data shown is applicable.
YES Calculator!
−424.13 J/mol⋅K
−212.07 J/mol⋅K
−848.26 J/mol⋅K
−1696.52 J/mol⋅K
8
Multiple Choice
NO Calculator!
2 Ag(s) + Br2(ℓ) → 2 AgBr(s)
H2(g) + I2(s) → 2 HI(g)
2 NO2(g) → N2O4(g)
He(g, 2 atm) → He(g, 10 atm)
9
Multiple Choice
Which of the following sets of conditions must be true for a reaction that is thermodynamically favorable only at relatively high temperatures?
-ΔG
-ΔH
-ΔS
-ΔG
+ΔH
+ΔS
+ΔG
-ΔH
-ΔS
+ΔG
+ΔH
+ΔS
10
Multiple Choice
An increase in temperature will increase the rate of
NO CALCULATOR:)
an ENDOthermic reaction ONLY
an EXOthermic reaction ONLY
BOTH ENDOthermic and EXOthermic reactions
NEITHER ENDOthermic nor EXOthermic reactions
11
Multiple Choice
In the reaction,
NO + O3 → NO2 + O2
the N atom in the NO molecule must strike a terminal O atom in the O3 molecule. Which of the diagrams below would most likely result in the formation of the products?
NO CALCULATOR:)
12
Multiple Select
A kinetics experiment is set up to measure the rate of the combustion of organic material (wood) with oxygen gas, O2, by measuring the volume of carbon dioxide gas, CO2, generated at 25°C and 1 atm as a function of time.
In general, which does NOT increase the rate of reaction?
Select ALL that apply
NO CALCULATOR:)
increasing the activation energy
increasing the temperature of the reaction
increasing the particle size by using a large block of wood instead of fine particles of sawdust
increasing the concentration of oxygen reacting with the organic material
13
Multiple Choice
A student collects the following kinetics data for a reaction. Based on the data, how would you classify the reaction? Why?
NO calculator!
First Order.
Concentration is halved after 3.00 min and again after another 3.00min. Thus the half-life of the reaction is constant, so the reaction is first order.
Zero Order.
Concentration is halved after 3.00 min and again after another 3.00min. Thus the half-life of the reaction is constant, so the reaction is zero order.
Second Order.
Concentration is halved after 3.00 min and again after another 3.00min. Thus the half-life of the reaction is constant, so the reaction is second order.
First Order.
ln(Concentration) is halved after 3.00 min and again after another 3.00min. Thus the half-life of the reaction is constant, so the reaction is first order.
14
Multiple Choice
The reaction pathways below represent the same reaction at the same temperature. Which represents the reaction in the presence of a catalyst?
15
Multiple Choice
Which of the following is a graph that describes the pathway of reaction that is exothermic and has a large activation energy?
16
Multiple Select
What must reactant particles achieve before a collision will be successful?
SELECT ALL THAT APPLY
Collide with enough energy that meets or exceeds the minimum activation energy.
Collide with the correct orientation.
Collide in a solution with at least the standard concentration.
Collide in the gas or aqueous phase, but not the solid or liquid phase.
Based on the information above, what is the standard enthalpy change for the following reaction?
N2H4(l) + H2(g) → 2NH3(g)
-151kJ/molrxn
-935kJ/molrxn
-1119kJ/molrxn
-59kJ/molrxn
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