
Energetics Revision Lesson
Presentation
•
Chemistry
•
9th - 12th Grade
•
Easy
Mike Litchfield
Used 3+ times
FREE Resource
9 Slides • 37 Questions
1
Energetics
Revision
2
Defintions
Topic 8 Energetics 1
Standard Enthalpy Changes of:
Reaction
Formation
Combustion
Neutralisation
3
Drag and Drop
4
Drag and Drop
5
Drag and Drop
6
Drag and Drop
7
Drag and Drop
8
Multiple Choice
For which equation is the enthalpy change correctly described as an enthalpy change of formation?
2NO(g) → N2(g) + O2 (g)
2CO(g) + O2(g) → 2CO2(g)
H2O(l) + NaCl (s) → NaCl(aq)
K(s) + Mn(s) +2O2(g) → KMnO4(s)
9
Multiple Choice
Which equation has an. enthalpy change of reaction which corresponds to the standard enthalpy change of atomization of chlorine?
1/2 Cl2(g) → Cl(g)
1/2 Cl2(l) → Cl(g)
Cl2(g) → 2Cl(g)
Cl2(l) → 2Cl(g)
10
Labelling
Label the following profile for the reaction:
CaCO3 --> CaO + CO2
Activation Energy
Products
Reactants
ΔH (negative)
ΔH (positive)
CaO + CO2
CaCO3
11
Labelling
Label the following profile for the reaction:
N2 + 3H2 --> 2NH3
ΔH (negative)
Reactants
Products
2NH3
N2 + 3H2
ΔH (positive)
Activation Energy
12
Multiple Select
The equation for a reaction is shown.
H2(g) + 1/2 O2(g) → H2O (l) ; ΔH = x kJ mol -1
Tick all that are correct.
It represents enthalpy change of formation only.
It represents enthalpy change of formation and combustion.
x is positive
x is negative
13
Multiple Choice
Which of the following processes is endothermic?
the condensation of steam
the freezing of water
the decomposition of calcium carbonate into calcium oxide and carbon dioxide
the reaction between hydrogen ions and hydroxide ions
14
Multiple Choice
The enthalpy change for the neutralization reaction below is − 114 kJ mol -1.
2NaOH (aq) + H2SO4(aq) ----> Na2SO4(aq) + 2H2O(l)
Use this information to suggest the most likely value for the enthalpy change for the following neutralization reaction.
Ba(OH)2 (aq) + 2HCl(aq) ----> BaCl2(aq) + 2H2O(l)
− 57 kJ mol -1
− 76 kJ mol -1
− 114 kJ mol -1
− 228 kJ mol -1
15
Multiple Choice
The enthalpy change for the neutralization reaction below is − 114 kJ mol -1.
2NaOH (aq) + H2SO4(aq) ----> Na2SO4(aq) + 2H2O(l)
Use this information to suggest the most likely value for the enthalpy change for the following neutralization reaction.
NaOH (aq) + HCl(aq) ----> NaCl(aq) + H2O(l)
− 57 kJ mol -1
− 76 kJ mol -1
− 114 kJ mol -1
− 228 kJ mol -1
16
Hess Cycles
Key Principle
The energy change for a reaction is the same, irrespective of the route taken, assuming the starting conditions are unaltered
17
18
Multiple Choice
-570
-790
-860
-1080
19
Draw
The enthalpy changes of formation of gaseous ethene and gaseous ethane are +52 kJ mol -1and − 85 kJ mol -1 respectively at 298 K.
What is the enthalpy change of reaction at 298 K for the following process?
C2H4(g) + H2(g) ---> C2H6(g)
Construct a Hess cycle and calculate.
20
Making an approximation for the enthalpy change of a reaction
Uses:
The heat energy required to break a mole of gaseous bonds homolytically in the gaseous state.
Definition
Bond Enthalpies
Limitations:
-bond enthalpies are averaged for all similar bonds
- energies are all in gaseous state
21
22
Drag and Drop
23
Multiple Choice
Which one of the following statements about an endothermic reaction is correct?
The energy absorbed in bond breaking is greater than the energy released in bond forming
The energy absorbed in bond breaking is less than the energy released in bond forming
The energy released in bond breaking is greater than the energy absorbed in bond forming
The energy released in bond breaking is less than the energy absorbed in bond forming
24
Drag and Drop
25
Multiple Choice
221.5
463.5
588
927
26
Multiple Choice
-95
-208
-1080
-93
27
Drag and Drop
1) The energy change is for
2) The bond enthalpies are
28
29
Multiple Choice
4.9
6.5
8.7
13.0
30
Multiple Choice
In an experiment, 1.000 g of a hydrocarbon, A, was burned completely in oxygen to produce 3.143 g of carbon dioxide and 1.284 g of water.
In a different experiment, the molar mass of the hydrocarbon, A, was found to be 84.0 g mol–1.
A spirit burner was filled with the liquid hydrocarbon, A. The burner was weighed, lit and then used to raise the temperature of a quantity of water in a beaker, as shown in the diagram. The burner was then reweighed.
Calculate the Enthalpy of Combustion - to an appropriate number of significant figures
-2790
-1860
-3650
-8670
31
Multiple Choice
Using 150ml of water, and 0.717g of methanol the heat transferred to the water was 9860J, calculate the enthalpy of combustion of methanol, include a sign and appropriate number of significant figures
-205
-450
-400
+320
+150
32
Dropdown
33
Lattice Enthalpy
Defintion
The change in heat energy when one mole of an ionic lattice is formed from its constituent gaseous ions.
e.g. Na+(g) + Cl-(g) --> NaCl(s)
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35
Multiple Choice
Na+ (g) + Cl- (g) --> NaCl (s)
Ionisation
Combustion
Lattice enthalpy
Atomisation
36
Multiple Choice
Mg (s) --> Mg (g)
Ionisation
Combustion
Formation
Atomisation
37
Multiple Choice
Cl (g) + e- --> Cl- (g)
Ionisation
Electron Affinity
Combustion
Formation
38
Multiple Choice
Mg (g) --> Mg+ (g) + e-
Ionisation
Combustion
Formation
Hydration
39
Multiple Choice
Na+ (g) + Cl- (g) --> Na+ (aq) + Cl- (aq)
Formation
Solution
Combustion
Hydration
40
Multiple Choice
½ H2 (g) + ½ Cl2 (g) --> HCl (g)
Formation
Combustion
Atomisation
Ionisation
41
Multiple Choice
O- (g) + e- --> O2- (g)
1st electron affinity
2nd electron affinity
3rd electron affinity
4th electron affinity
42
Multiple Choice
C (g)+ O2 (g)--> CO2 (g)
Ionisation
Combustion
hydration
solution
43
Multiple Choice
First electron affinity of an element is usually ________ and second electron affinity is ____________.
exothermic, endothermic.
exothermic, exothermic.
endothermic, endothermic.
endothermic, exothermic.
44
Multiple Choice
What enthalpy change does the number 4 represent?
Formation
1st ionisation energy of Na
1st electron affinity of Na
Atomisation of Na
45
Multiple Choice
Identify the enthalpy change represented by letter g.
Enthalpy of formation
Lattice Enthalpy
Electron affinity of bromine
Enthalpy of atomisation of zinc
46
Multiple Choice
Enthalpy change is represented by step y ?
Enthalpy of formation calcium bromide
Enthalpy of atomisation of calcium
1st electron affinity of bromine
Enthalpy of atomisation of bromine
Energetics
Revision
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