
organic Chemistry Via Enolate
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Chemistry
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University
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Hard
Dr Bhovi
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4 Slides • 3 Questions
1
UNIT-II: ORGANIC CHEMISTRY-6
Presented :
Dr.Venkatesh K Bhovi M.Sc.,Ph.D..PDF(IITM,KUD,FIN)
Asst. Professor of Chemistry
Vijayanagara College, Hosapete
2
The acidity of α-H atoms in Ethyl Acetoacetate
Due to the presence of the Electron withdrawing group, the EWG Methylene group is present in between the two electron group the hydrogen bond bonded to carbon become weak. Due to weak-boned hydrogen, it is easily deprotonated from the methylene group. Therefore it acts as acidic—the extent of methylene proton acidity depends on the attaching group's nature.
3
When two moles of ethylacetate react with Ethoxide (NaOH+ EtOH= NaOEt), it underwent self condensation reaction, followed by acidification give raised to corresponding β-Ketoester
Claisen condensation Reaction Mechanism
4
Multiple Choice
Ethyl acetate can be converted into on-base hydrolysis
ester
Alkyl acid
amine
ketone
5
Fill in the Blanks
Type answer...
6
Open Ended
Ethyl acetoacetate exists in which state
7
Thank you
any question are their contact 7854621510
UNIT-II: ORGANIC CHEMISTRY-6
Presented :
Dr.Venkatesh K Bhovi M.Sc.,Ph.D..PDF(IITM,KUD,FIN)
Asst. Professor of Chemistry
Vijayanagara College, Hosapete
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